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</div> </h1> </div> </div> <ul class="e_box p_dataSource borderT_default" data-ename="資訊信息"> <li id="cyga22e" class="sort"><span id="cyga22e" class="i_sort">分類(lèi)：</span><a href="/news/3/">行業(yè)新聞</a></li> <li id="cyga22e" class="auth"><span id="cyga22e" class="i_auth">作者：</span></li> <li id="cyga22e" class="source"><span id="cyga22e" class="i_source">來(lái)源：</span></li>  <li id="cyga22e" class="date"><span id="cyga22e" class="i_pubDate">發(fā)布時(shí)間：</span>2020-12-28</li> <li id="cyga22e" class="pvs"><span id="cyga22e" class="i_pvs">訪(fǎng)問(wèn)量：</span><span id="cyga22e" class="p_viewCount">0</span></li> </ul>  <p class="e_article p_summary background_info" data-ename="資訊概要信息"> <span><span id="cyga22e" class="i_SummaryBox">【概要描述】</span></span>在污水處理中，含氰電鍍廢水的處理非常重要，一旦處理技術(shù)選擇不當，可能會(huì )影響處理的整體效果，繼而引發(fā)嚴重的水體污染問(wèn)題。利用電化學(xué)氧化法進(jìn)行含氰電鍍廢水的處理，能夠確保處理后的廢水達到排放標準，不過(guò)在技術(shù)應用過(guò)程中，應該明確工藝條件對于處理效果的影響，做好相應調整和優(yōu)化，確保處理效果能夠達到最佳化。 </p>  </div>  <div id="cyga22e" 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</div> <div id="cyga22e" class="swiper-container gallery-thumbs"> <div id="cyga22e" class="swiper-wrapper"> <div data-foreachitem class="swiper-slide"> <div id="cyga22e" class="p_sImgBox"> <img src="/upload/s.png" lazy-src="http://img201.yun300.cn/repository/image/fwUZ-X9lQm-4g5l8WTnHRw.jpg_{i}xaf.jpg?tenantId=219141&viewType=1" class='js_thumb' title= alt= /> </div> </div> </div>   </div> </div> <div id="cyga22e" class="e_box p_infoBox">  <div id="cyga22e" class="e_box p_header">   <div id="cyga22e" class="e_box p_TitleBoxA"> <h1 class="e_title p_headA h3 font_thick"> <div id="cyga22e" class="font"> <i class="iconfont"></i> 電化學(xué)氧化法處理含氰電鍍廢水的應用 </div> </h1> </div> </div>  <p class="e_article p_summary" data-ename="資訊概要信息"> <span><span id="cyga22e" class="i_SummaryBox">【概要描述】</span></span>在污水處理中，含氰電鍍廢水的處理非常重要，一旦處理技術(shù)選擇不當，可能會(huì )影響處理的整體效果，繼而引發(fā)嚴重的水體污染問(wèn)題。利用電化學(xué)氧化法進(jìn)行含氰電鍍廢水的處理，能夠確保處理后的廢水達到排放標準，不過(guò)在技術(shù)應用過(guò)程中，應該明確工藝條件對于處理效果的影響，做好相應調整和優(yōu)化，確保處理效果能夠達到最佳化。 </p> <ul class="e_box p_dataSource e_box p_dataSource borderB_default" data-ename="資訊信息"> <li id="cyga22e" class="sort"><span id="cyga22e" class="i_sort">分類(lèi)：</span><a href="/news/3/">行業(yè)新聞</a></li> <li id="cyga22e" class="auth"><span id="cyga22e" class="i_auth">作者：</span></li> <li id="cyga22e" class="source"><span id="cyga22e" class="i_source">來(lái)源：</span></li>  <li id="cyga22e" class="date"><span id="cyga22e" class="i_pubDate">發(fā)布時(shí)間：</span>2020-12-28</li> <li id="cyga22e" class="view"><span id="cyga22e" class="i_pvs">訪(fǎng)問(wèn)量：</span><span id="cyga22e" class="p_viewCount">0</span></li> </ul>  </div>  <div id="cyga22e" class="e_title p_articlesTitle" data-ename="描述標題"> <div id="cyga22e" class="font">詳情 </div> </div> <div id="cyga22e" class="e_box p_articles" data-ename="資訊詳細描述"><div id="cyga22e" class='reset_style js-reset_style js-adapMobile '><div> 　　在污水處理中，含氰電鍍廢水的處理非常重要，一旦處理技術(shù)選擇不當，可能會(huì )影響處理的整體效果，繼而引發(fā)嚴重的水體污染問(wèn)題。利用電化學(xué)氧化法進(jìn)行含氰電鍍廢水的處理，能夠確保處理后的廢水達到排放標準，不過(guò)在技術(shù)應用過(guò)程中，應該明確工藝條件對于處理效果的影響，做好相應調整和優(yōu)化，確保處理效果能夠達到最佳化。</div> <div> 　　電化學(xué)氧化法對含氰電鍍廢水的處理，主要是在電解過(guò)程中，向廢水中加入相應的氯化鈉作為輔助劑，在電解時(shí)產(chǎn)生氧化劑氯氣及次氯酸根，能夠對氰離子質(zhì)量濃度不超過(guò) 500mg/L 的電鍍廢水進(jìn)行處理。相比較而言，直接電化學(xué)氧化法則能夠對氰離子質(zhì)量濃度超過(guò) 1000mg/L 的電鍍廢水進(jìn)行處理。在陽(yáng)極氧化作用下，氰離子能夠被轉化為氰酸根離子，依照不同的 pH 值，還可以進(jìn)一步氧化為不同的產(chǎn)物，如二氧化碳與氮氣、銨根離子與草酸鹽、銨根離子與碳酸鹽等。</div> <div> 　　電化學(xué)氧化法的基本原理，是在電解槽內設置有機物溶液或者懸浮液，接通直流電后，可以在陽(yáng)極上奪取電子，將有機物氧化或者向將低價(jià)金屬氧化成高價(jià)金屬離子，然后再將有機物氧化。依照電解方式的不同，借以將電化學(xué)氧化法分為直接電解氧化和間接電解法，其在富營(yíng)養化水體處理中有著(zhù)較為廣泛的應用，相比較傳統工藝，電化學(xué)氧化法不需要直接投加化學(xué)物質(zhì)，也不需要使用微生物，不僅操作簡(jiǎn)單，控制容易，而且反應速度更快，優(yōu)點(diǎn)相當明顯。</div> <div> 　　選擇了間歇電化學(xué)氧化法，將電流密度控制在 50mA/c㎡，需要處理的廢水體積為 200mL，將廢水溫度控制在 25℃左右。將 Ti/PbO2-F、Ti/RuO2-TiO2-SnO2 電極作為陽(yáng)極，陽(yáng)極規格為 3cm×3cm。將 Fe、Ti、石墨電極作為陰極，規格與陽(yáng)極相同。將電極間距調整到 0.5cm，然后進(jìn)行鼓氣攪拌工作。在實(shí)驗中，可以通過(guò)對陽(yáng)極和陰極材料、pH 值、氯離子質(zhì)量濃度等，對電鍍廢水中氰離子及 COD 的去除效果進(jìn)行分析和研究。</div> <div> 　　將 Ti/RuO2-TiO2-SnO2 電極作為陽(yáng)極，進(jìn)行 3h 的電解處理，測定處理后的廢水，氰離子質(zhì)量濃度為 14.76mg/L，COD 質(zhì)量濃度為 159mg/L；將 Ti/PbO2-F 電極作為陽(yáng)極，同樣電解 3h，氰離子質(zhì)量濃度為 39.73mg/L，COD 質(zhì)量濃度為 172mg/L。對比兩種結果，Ti/RuO2-TiO2-SnO2 電極較Ti/PbO2-F 電極的處理效果更好，分析原因，主要是 Ti/PbO2-F 電極本身屬于非活性電極，活性電位較高，Ti/RuO2-TiO2-SnO2 電極則屬于活性電極，在析氯、析氧過(guò)程中有著(zhù)較為廣泛的應用。不僅如此，Ti/RuO2-TiO2-SnO2 電極在降解的過(guò)程中，槽電壓更低，因此選擇其作為陽(yáng)極。</div> <div> 　　不同 pH 值對廢水處理效果有著(zhù)不同的影響，當 pH 值為 8 時(shí)，電解 3h，氰離子質(zhì)量濃度為 22.86mg/L；當 pH 值為 10 時(shí)，電解 3h，氰離子質(zhì)量濃度為 14.76mg/L；當 pH 值為 12 時(shí)，電解3h，氰離子質(zhì)量濃度為27.40mg/L。對比三種不同的結果，可以看出，當pH值為10時(shí)，能夠獲得最佳降解效果，無(wú)論是氰離子還是COD，都能夠達到最高去除率，能耗也較低。對比四種陰極材料，發(fā)現除 Pb 外，其他三種材料的槽壓并沒(méi)有很大區別，Fe 陰極的槽壓最低，表明其降解效果最好，石墨陰極的效果最差。</div> <div> 　　在相關(guān)研究中，Meier K 利用 IrO2-Pt/Ti 電極作為陽(yáng)極，將 Fe、Cu、Ti 等作為陰極，分析其對于硝酸鹽還原效果的影響，結果表明，按照去除率從低到高的順序，以此為 Ti、Cu 和 Fe，金屬電極的導電能力能夠直接決定被處理對象在電極上得到電子的能力，陰極材料的活躍性越強，電解過(guò)程中達到陰極的電子越容易釋放，能夠生成原子態(tài)的氫，還原性較強，因此，這里選擇 Fe 作為陰極材料。</div> <div> 　　因此，在利用電化學(xué)氧化法對含氰廢水進(jìn)行處理時(shí)，應該盡量選擇堿性環(huán)境，如果pH值偏低，則會(huì )影響氯對于氰離子的氧化作用，加上陽(yáng)極表面存在的OH-放電，陽(yáng)極去pH值會(huì )伴隨著(zhù)降解過(guò)程的深入逐漸下降。當pH值降低到酸性（7以下）時(shí)，廢水處理過(guò)程中將會(huì )釋放劇毒氫氰酸氣體，對周邊環(huán)境造成污染。不過(guò)，過(guò)高的p H值會(huì )對電極產(chǎn)生腐蝕，同樣會(huì )影響降解的效果，在這種情況下，可以將pH值控制為10。</div> <div> 　　利用 Fe 或者 Ti 作為陰極，進(jìn)行 3h 電解處理，測定處理后的廢水，氰離子質(zhì)量濃度為 27.48mg/L 和 16.95mg/L，COD 質(zhì)量濃度為 170mg/L和 176mg/L；利用 Pb 或者石墨作為陰極，電解 3h 后，氰離子質(zhì)量濃度為 28.6mg/L 和 29.1mg/L，COD 質(zhì)量濃度為 181mg/L 和 197mg/L。</div> <div> 　　在沒(méi)有加入氯化鈉的情況下，電解 3h，氰離子質(zhì)量濃度為 4.41mg/L，COD 質(zhì)量濃度為 250mg/L；加入 0.5g/L 的氯化鈉，電解 3h，氰離子質(zhì)量濃度為 1.90mg/L，COD 質(zhì)量濃度為 214mg/L；加入 1.0g/L 氯化鈉，電解3h，氰離子質(zhì)量濃度為 0.15mg/L，COD 質(zhì)量濃度為 154mg/L?？梢悦黠@看出，在加入氯離子后，氰離子和 COD 的去除效率都有所增加，分析原因，主要是因為電化學(xué)反應本身較為復雜，在氯離子加入后，不僅會(huì )在電極表面進(jìn)行直接的電化學(xué)氧化，還會(huì )在 Cl-/Cl2 或者 Cl-/ClO-之間進(jìn)行間接電化學(xué)氧化。</div> <div> 　　當溶液中 Cl-的質(zhì)量濃度足夠高時(shí)，會(huì )在電化學(xué)氧化的過(guò)程中產(chǎn)生 Cl2 以及 ClO-，這些產(chǎn)物都能夠幫助降低廢水中 COD的質(zhì)量濃度?；诖?，在 Cl-質(zhì)量濃度較高的情況下，COD 也會(huì )有著(zhù)較高的去除率。相關(guān)研究文獻指出，若溶液中 Cl-質(zhì)量濃度達到 CN- 的 3-5倍，氰離子和 COD 都可以獲得較高的去除率，而在氯離子加入后，電解液的電導率會(huì )有所增加，槽壓的降低有助于降低能源消耗。</div> </div></div>  <div id="cyga22e" class="e_box p_QRCode borderT_default" data-ename="打開(kāi)手機查看"> <p class="e_title p_SaveText" data-ename="二維碼引導信息"><span id="cyga22e" class="i_qrcode">掃二維碼用手機看</span></p> <p class="e_image js_qrcode" data-ename="二維碼"></p> </div>  <div id="cyga22e" class="e_box d_pcDom p_PrevAndNext borderB_default" data-ename="上一篇、下一篇信息區"> <div id="cyga22e" class="e_box p_previewBox"> <span id="cyga22e" class="i_title"><span id="cyga22e" class="i_pageUpTitle">上一個(gè)</span><span id="cyga22e" class="clons">:</span></span> <a href="/news/10.html" data-ename="上一篇信息區"> <span id="cyga22e" class="p_PreviewTitle">2021潤滑油漲價(jià)已成定局！</span> </a> </div>  <div 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